Download for major hugeness. (May stab your internet in the eyes, though...)
Character Nagato Yuki from The Suzumiya Haruhi series.
This particular screenshot is from the Disappearance of Haruhi Suzumiya movie. [link]
Surprisingly, this picture only took a few hours to make, from start to finish. The snow was really a lot of fun; I used the "Fuzzytastic" brush, then blurred varying sizes to give the illusion of depth from the "cameras" focus.
Enjoy your brand new desktop!!
Used mostly Paint Tool SAI, but also used Photoshop CS4 for the blurring.